Atomic Structure: Electron Shells 

Read the pages indicated by A-3 concerning electron shells and study behavioral objective 8

 How many electrons are located in an atom? Remember the atomic number refers to the number of protons (positive charges) and that all  atoms are neutral; therefore,  the number of electrons must be equal to the number of protons. 
(an atom with an atomic number of 19 contains 19 electrons; an atom containing 7 protons and 9 neutrons contains 7 electrons)

How are the electrons arranged in an atom? 

In orbit around the nucleus, the negatively charged electrons form an electron cloud. This cloud has distinct layers called shells. These shells have numerical designations. The shell closest to the nucleus is the first shell, the second closest the second and so forth. An older naming scheme has the closest shell called the K shell, the second closest the L shell, then the M and N shell and so forth in that order. Each of the shells have different energy levels. Electrons load or fill these shells in a definite fashion. There is a particular numerical limit or capacity that each shell has for electrons. 

The 1st shell (K shell) can hold a maximum of 2 electrons, the second shell (L shell) can hold a maximum of 8 electrons, the third shell (M shell) can hold a maximum of 18 electrons, the fourth shell (N shell) can hold a maximum of 32 and so on. Electrons will almost always fill an inner shell completely before going an outer shell. The first shell will fill before the second, the second before the third until all the available electrons are used. There is a formula that can be used to determine how the shells are filled. 

 

X = 2N2

where 
X = the maximum number of electrons in the shell 
N = the shell number 

 example 1: Determine the maximum number of electrons possible in the 1st shell. (K shell) 

 

X = 2 * 11 
X = 2
example 2: Determine the maximum number of electrons possible in the 2nd shell. (L shell) 

 

X = 2 * 22 
X = 8
example 3: Determine the maximum number of electrons possible in the 4th shell. (N shell) 

 

X = 2 * 42 
X = 32
Important: Even though the third and fourth shell can hold a maximum of 16 and 32 electrons, the maximum number of electrons they can hold when they are an outer shell is eight! What happens in filling these shells is: once you have placed eight electrons in the outer shell place the next two electrons in the next shell, making it the outer shell, than go back to the original shell and complete filling it. 

  
19. Based upon the above information, Lithium, which has an atomic number of 3, would have how many shells to fill and how many would go into each shell? 

 

a) 3 shells, 1, 2, and 3, with 1 electron in each 
b) 1 shell, the K shell with all 3 electrons in it 
c) 2 shells, with 2 electrons in the first and 1 electron in the second 
Draw the structure of this atom in your notes. 

 

Press here to check your answer. 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

  
20. Magnesium, whose atomic number is 12, has how many electron shells? 

 

a) 5 
b) 3 
c) 7 
Draw the structure of this atom in your notes. 

 Press here to check your answer. 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

  

21. How many electrons would go into which shells for the element chlorine (atomic number = 17)? 

 

a) 2 electrons in the first, 8 electrons in the 2nd, and 7 electrons in the 3rd 
b) 2 electrons in the K shell, and 5 electrons each in the L and M shells 
c) 4 electrons in the 1st shell, and 2 electrons in each of the last 6 shells 
Draw the structure of this atom in your notes. 

 Press here to check your answer. 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

  
The following is a table of the 1st 20 elements showing their electron distribution. 

 
  ELEMENT   SYMBOL   ATOMIC   
  NUMBER
(K SHELL 
1ST SHELL
(L SHELL)  
 2ND SHELL
( M SHELL
3RD SHELL
(N SHELL) 
4TH SHELL
Hydrogen       H        1        1      
Helium       He         2        2      
Lithium       Li        3        2          1    
Beryllium       Be        4         2          2    
Boron       B         5        2          3     
Carbon       C        6        2          4    
Nitrogen       N         7        2          5    
Oxygen       O        8         2          6    
Fluorine       F        9        2           7    
Neon       Ne       10        2          8    
Sodium       Na       11        2          8          1  
Magnesium       Mg       12        2           8          2   
Aluminum       Al       13         2          8          3  
Silicon       Si       14        2          8          4  
Phosphorus       P       15        2          8           5   
Sulfur       S       16        2          8          6  
Chlorine       Cl       17        2          8          7  
Argon       Ar       18        2          8          8  
Potassium       K       19         2          8          8         1
Calcium       Ca       20        2          8          8         2 
Important: Even though the third and fourth shell can hold a maximum of 16 and 32 electrons, the maximum number of electrons they can hold when they are an outer shell is eight! What happens in filling these shells is: once you have placed eight electrons in the outer shell place the next two electrons in the next shell, making it the outer shell, than go back to the original shell and complete filling it. (Observe this pattern in the table above - potassium and calcium) 

 With the aid of the chart above draw the atomic structure of the first twenty elements showing the arrangement of the electrons in their proper shells. 

 22. Which of the following statements is NOT true concerning the arrangement of electrons in an atom? 

a) The first shell can only hold either one or two electrons. 
b) The second shell can hold anywhere from one to eight electrons. 
c) The third shell can hold anywhere from one to eight electrons when its an outer shell. 
d) The third shell can hold anywhere from one to sixteen when there is a fourth shell. 
e) All outer shells of an atom must have eight electrons. 
Press here to check your answer. 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

  
In the next lesson bonding will be explained. To understand how atoms bond to form molecules you will need to determine the number of electrons in an atoms outer shell or valence shell. 

 Read behavioral objective 9 and 10

 CHEMICAL SHORTHAND 

 The 103 or so elements that have been discovered have a variety of names some of which are quite long. Trying to use these names to refer to these elements on an everyday basis would not be very practical. The use of symbols to represent these elements is used makes for a far more efficient method when referencing them as individual elements or when they combine with each other forming compounds

 An abbreviation is used in place of the full name. This abbreviation usually is the first one or two letters of the elements name. Carbon, for instance, uses a capital C as its symbol. Oxygen uses a capital O and hydrogen uses a capital H.  There are some elements that do not follow this rule. Sodium uses Na as its symbol, deriving this from the Latin word Natrium. Potassium obtains its symbol, K, from the Latin word Kalium. 

 The following table illustrates the use of symbols for the first forty elements: 

 
    ELEMENT     SYMBOL     ELEMENT      SYMBOL
    Hydrogen            H      Scandium            Sc
    Helium            He       Titanium            Ti
    Lithium            Li      Vanadium             Va 
    Beryllium            Be      Chromium            Cr
    Boron            B       Manganese            Mn
    Carbon            C       Iron            Fe
    Nitrogen            N      Cobalt            Co
    Oxygen            O      Nickel             Ni
    Fluorine            F      Copper            Cu
    Neon            Ne      Zinc             Zn
    Sodium            Na      Gallium            Ga
    Magnesium            Mg      Germanium            Ge
    Aluminum            Al      Arsenic            As
    Silicon            Si      Selenium            Se
    Phosphorus            P      Bromine            Br
    Sulfur            S      Krypton            Kr 
    Chlorine            Cl      Rubidium            Rb 
    Argon            Ar       Strontium            Sr
    Potassium            K      Yttrium             Y
    Calcium            Ca       Zirconium            Zr
 
A molecular formula is where the number of atoms for each element present in a molecule is indicated by subscripts. 

 C52H128O9N4Mg is the molecular formula for chlorophyll. 

 This formula indicates that one molecule of chlorophyll consists of 52 carbon atoms, 128 hydrogen atoms, 9 oxygen atoms, 4 nitrogen atoms, and 1 magnesium atom. 

 23. Which elements are present in the following molecule? 

 MgCl2 

 Press here to check your answer. 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

  
24. The molecular formula for glucose is C6 H12 O6

 Which elements are present in glucose? 

 Press here to check your answer. 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

  
A molecular formula is where the number of atoms for each element present in a molecule is indicated by subscripts. 

 25. Write a formula showing the following arrangement of atoms.  Table sugar, sucrose, contains twelve atoms of carbon, twenty two atoms of hydrogen and eleven atoms of oxygen. Indicate two molecules. 

 Press here to check your answer. 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


This is the end of the second lesson. The two molecular formulas above demonstrate two molecules containing atoms bonded together by ionic or covalent bonding. The next lesson will explain how ionic bonds are formed. 

You must answer the following question correctly to go to the Biology 108N home page and to lesson three, ionic bonding. 

 26. Based upon the above information, oxygen, which has an atomic number of 8 and atomic weight of 16 amu would have how many protons, neutrons, electrons, electrons in outer shell? 

                     protons      neutrons       electrons        outer shell electrons 
 
            a )         24               8                   16                     6 
            b )           8               8                     8                    6 
            c )           8              16                    8                     4 

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Created by the Center for Learning Technologies, Academic Technology Services.  
Last modified October 22, 1997.